
基本信息:
- 专利标题: 碳纳米管增韧SiBCN(O)金属基陶瓷涂层及其制法
- 申请号:CN201710839455.6 申请日:2017-09-18
- 公开(公告)号:CN107540399B 公开(公告)日:2020-01-17
- 发明人: 王斌 , 冯颖
- 申请人: 中科院广州化学有限公司南雄材料生产基地 , 中科院广州化学有限公司
- 申请人地址: 广东省韶关市南雄市珠玑工业园(广东南雄精细化工基地)
- 专利权人: 中科院广州化学有限公司南雄材料生产基地,中科院广州化学有限公司
- 当前专利权人: 国科广化(南雄)新材料研究院有限公司,中科院广州化学有限公司
- 当前专利权人地址: 广东省韶关市南雄市珠玑工业园(广东南雄精细化工基地)
- 代理机构: 广州市华学知识产权代理有限公司
- 代理人: 郭炜绵; 裘晖
- 主分类号: C04B35/80
- IPC分类号: C04B35/80 ; C04B35/58 ; C04B35/622
The invention discloses a carbon nano tube toughened SiBCN(O) metal-based ceramic coating and a preparation method thereof. The preparation method comprises the following steps: ammonolyzing vinyl chlorosilane and phenyl chlorosilane with ammonia, and then carrying out reaction for 1 to 3 hours; removing a solvent through evaporation, thus obtaining liquid polysilazane, and dropwise adding boranedimethyl sulfide for continuous reaction, thus obtaining polyborosilazane; dropwise adding a carbon nano tube solution into the polyborosilazane solution, and carrying out stirring, thus obtaining polymer slurry; coating the surface of a matrix with the slurry, and carrying out pyrolysis at high temperature to obtain the SiBCN(O) metal-based ceramic coating. According to the carbon nano tube toughened SiBCN(O) metal-based ceramic coating disclosed by the invention, the polyborosilazane synthesized by the vinyl chlorosilane, the phenyl chlorosilane and the borane dimethyl sulfide is used as a raw material, and carbon nano tubes are added to prepare the slurry; after immersion coating is carried out, high-temperature pyrolysis is carried out, thus obtaining the high-temperature-resistant andcorrosion-resistant ceramic coating. The process is easy to operate, and the sintering temperature is low; the energy consumption is reduced, and the cost is saved.
公开/授权文献:
- CN107540399A 碳纳米管增韧SiBCN(O)金属基陶瓷涂层及其制法 公开/授权日:2018-01-05