
基本信息:
- 专利标题: 一种从含溴废水中回收溴素的方法
- 专利标题(英):Method for recycling bromine from bromine-containing wastewater
- 申请号:CN201310549773.0 申请日:2013-11-07
- 公开(公告)号:CN103613072A 公开(公告)日:2014-03-05
- 发明人: 李伟 , 陈吕军 , 李荧 , 郑炜
- 申请人: 浙江双益环保科技发展有限公司
- 申请人地址: 浙江省嘉兴市亚太路705号浙江清华长三角研究院总部创新大厦501室
- 专利权人: 浙江双益环保科技发展有限公司
- 当前专利权人: 浙江双益环保科技发展有限公司
- 当前专利权人地址: 浙江省嘉兴市亚太路705号浙江清华长三角研究院总部创新大厦501室
- 主分类号: C01B7/09
- IPC分类号: C01B7/09
The invention relates to a method for recycling bromine from bromine-containing wastewater, which comprises the following steps: acidification: adding hydrochloric acid or sulfuric acid into industrial wastewater containing bromide ions to adjust the pH value of the industrial wastewater to 3-5; oxidation: adding an oxidizing agent into the acidified industrial wastewater for oxidation to generate bromine; extraction: adopting n-dodecane as an extraction agent, adding n-dodecane into the oxidized industrial wastewater, and extracting bromine from an aqueous phase to an n-dodecane phase; liquid separation: performing liquid separation on the two-phase solution added with the extraction agent, wherein the upper layer is an oil phase, namely a bromine and n-dodecane solution, and the lower layer is an aqueous phase; separating the aqueous phase from the oil phase; rectification: rectifying the n-dodecane and bromine solution obtained by the liquid separation so that bromine is separated from n-dodecane to obtain a bromine product. In the method provided by the invention, bromine is extracted by a solvent extraction process; compared with the traditional bittern bromine extraction technology, the use of steam is greatly saved, the cost of whole bromine extraction is remarkably reduced, and better economic benefits are obtained.