
基本信息:
- 专利标题: 一种环氧树脂反应型微胶囊阻燃剂及其制备方法
- 专利标题(英):Epoxy resin reaction-type microcapsule fire retardant and preparation method thereof
- 申请号:CN201210048542.7 申请日:2012-02-28
- 公开(公告)号:CN102585292A 公开(公告)日:2012-07-18
- 发明人: 沈敏敏 , 张延奎 , 吴昆 , 魏续瑞
- 申请人: 中科院广州化学有限公司
- 申请人地址: 广东省广州市天河区兴科路368号
- 专利权人: 中科院广州化学有限公司
- 当前专利权人: 中科院广州化学有限公司
- 当前专利权人地址: 广东省广州市天河区兴科路368号
- 代理机构: 广州市华学知识产权代理有限公司
- 代理人: 裘晖
- 主分类号: C08K9/10
- IPC分类号: C08K9/10 ; C08K3/32 ; C08L63/00 ; C08K13/06
The invention belongs to the field of polymer flame retardation and discloses an epoxy resin reaction-type microcapsule fire retardant and a preparation method thereof. The epoxy resin reaction-type microcapsule fire retardant is characterized in that at least one phosphorus-containing fire retardant is utilized as a capsule core; a product of a reaction of at least one curing agent, an epoxy resin and triglycidyl isocyanurate is utilized as a capsule material; a mass ratio of the capsule material to the capsule core is (0.05 to 0.4): 1; and a mass ratio of the epoxy resin to the triglycidyl isocyanurate is (0 to 6): 1. The preparation method provided by the invention comprises the following steps of dispersing the at least one phosphorus-containing fire retardant in at least one solvent,heating, adding a triglycidyl isocyanurate solution and an epoxy resin solution into the heated solution, stirring for a reaction for 10 to 30 minutes, dropwisely adding a curing agent solution into the reaction system, carrying out a reaction process for 1 to 2 hours, heating to a temperature of 70 to 78 DEG C, carrying out a reaction process for 2 to 12 hours, cooling, filtering, washing and drying to obtain the epoxy resin reaction-type microcapsule fire retardant. The epoxy resin reaction-type microcapsule fire retardant has uniform granularity, good liquidity, low water-solubility and good polymer compatibility. Through utilization of the epoxy resin reaction-type microcapsule fire retardant, good flame resistance, good water tolerance and good mechanical properties are obtained.
公开/授权文献:
- CN102585292B 一种环氧树脂反应型微胶囊阻燃剂及其制备方法 公开/授权日:2013-08-07
IPC结构图谱:
C | 化学;冶金 |
--C08 | 有机高分子化合物;其制备或化学加工;以其为基料的组合物 |
----C08K | 使用无机物或非高分子有机物作为配料 |
------C08K9/00 | 使用预处理的配料 |
--------C08K9/10 | .包胶的配料 |